Tungsten anchored onto functionalized SBA-15: an efficient catalyst for diastereoselective synthesis of 2-azapyrrolizidine alkaloid scaffolds

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An Efficient Protocol for Synthesis of 2-amino-3cyanopyridine Derivatives using Nano-modified SBA-15

Condensation reaction of chalcones with malononitrile and ammonium acetate in the presence of the green nano-modified SBA-15 affords the corresponding 2-amino-3-cyanopyridine derivatives in excellent yield. This approaches claimed to be an environment friendly protocol as it afforded some advantages such as excellent yields and cleaner reaction.

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Brønsted Acidic Phosphonium Based Ionic Liquid Functionalized SBA-15 [HO3S-PhospIL@SBA-15]: Green, Recyclable, and Efficient Catalyst for the Synthesis of Pyrano[3,2-c]Chromenone Derivatives

The surface of SBA-15 was modified by diphenylphosphine; then, it was treated with butane sultone and sulfuric acid to obtain Brønsted acid HO3S-phosphonium based ionic liquid functionalized SBA-15 with HSO4- as a counteranion. It efficiently catalyzed synthesis of pyrano[3,2-c]chromenone derivatives through the reaction of 4-hydroxycoumarin and chalcones at...

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SBA-15-supported-dithizone-copper(I): An efficient heterogeneous catalyst for synthesis of 1,4-disubstituted 1,2,3-triazoles in water

In this work, the SBA-15-supported dithizone-copper(I) [SBA-15-dtz–Cu(I)] complex as a new heterogeneous catalyst is prepared for the first time. The catalyst prepared is characterized by the FT-IR spectroscopy, SEM, and ICP techniques. This reusable heterogeneous catalyst can be used in the click reactions for the green and facile synthesis of 1,4-disubstituted 1,2,3-triazolesvia a on...

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ژورنال

عنوان ژورنال: RSC Advances

سال: 2019

ISSN: 2046-2069

DOI: 10.1039/c9ra02825k